Quantum Physics

   

Quantum-Mechanical Analysis of the MO Method and VB Method from the Position of PQS.

Authors: Bezverkhniy Volodymyr Dmytrovych, Bezverkhniy Vitaliy Volodymyrovich.

The MO method and the VB method are analyzed using the principle of quantum superposition (PQS) and the method of describing a quantum system consisting of several parts. It is shown that the main assumption of the molecular orbitals method (namely, that the molecular orbital can be represented like a linear combination of overlapping atomic orbitals) enters into an insurmountable contradiction with the principle of quantum superposition. It is also shown that the description of a quantum system consisting of several parts (adopted in quantum mechanics) actually prohibits ascribe in VB method to members of equation corresponding canonical structures.

Comments: 9 Pages.

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Submission history

[v1] 2017-04-05 23:34:04

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